Al-TiC composites In Situ-processed by ingot metallurgy and rapid solidification technology: Part I. Microstructural evolution |
| |
Authors: | X C Tong H S Fang |
| |
Affiliation: | (1) Department of Materials Science and Engineering, University of Michigan, 48109-2136 Ann Arbor, MI;(2) Present address: the Department of Materials Science and Engineering, Tsinghua University, 100084 Beijing, People’s Republic of China |
| |
Abstract: | The present work was undertaken to highlight a novel in situ process in which traditional ingot metallurgy plus rapid solidification techniques were used to produce Al-TiC composites
with refined microstructures and enhanced dispersion hardening of the reinforcing phases. Microstructures of the experimental
materials were comprehensively characterized by optical microscopy, electron microscopy, and X-ray diffraction. The results
show that the in situ-synthesized TiC particles possess a face-centered cubic crystal structure with an atomic composition of TiC0.8 and a lattice parameter of 0.431 nm. The typical ingot metallurgy microstructures exhibit aggregates of TiC particles segregated
generally at the α-Al subgrain or grain boundaries and consisting of fine particles of 0.2 to 1.0 μm in size. The rapidly solidified microstructures formed under certain thermal history conditions contained a uniform, fine-scale
dispersion of TiC phase particles with a size range of 40 to 80 nm in an α-Al supersaturated matrix of 0.30 to 0.85 μm in grain size. These dispersed TiC particles generally have a semicoherent relationship with the α-Al matrix. Based on the experimental results, a comprehensive kinetic mechanism of in situ TiC synthesis, which includes a solid-liquid interface reaction between the carbon particles and the Al melt and multiple
nucleation and growth of TiC from the Al melt, was proposed. Then, the evolution of the aggregate TiC particles in a superheated
melt before rapid solidification, i.e., dissolution, nucleation, and growth of the regenerated TiC dispersed particles, was analyzed. Furthermore, the behavior
of rapid solidification kinetics, the nucleation of α-Al on TiC-dispersed particles, and the interaction between TiC particles and the solidification front were documented experimentally
and theoretically. These studies provided the theoretical criteria and an experimental basis for the optimum design of this
kind of composite. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|