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用于钙钛矿太阳能电池光阳极的TiO2/ZnTiO3复合物的制备与性能
引用本文:徐艳,张翁晶,胡木林.用于钙钛矿太阳能电池光阳极的TiO2/ZnTiO3复合物的制备与性能[J].材料导报,2016,30(20):21-25.
作者姓名:徐艳  张翁晶  胡木林
作者单位:华中科技大学材料科学与工程学院,武汉,430074
摘    要:利用溶胶-凝胶法制备一系列不同Zn/Ti物质的量比的TiO_2/ZnTiO_3复合粉体,并借助XRD分析粉末的晶体结构。将复合粉末制备成膜作为钙钛矿太阳能电池的光阳极,通过SEM表征复合膜的表面形貌,并对所组装电池的性能进行测试。结果显示,Zn/Ti物质的量比对电池的性能有很大影响,当n(Zn)∶n(Ti)=1∶6时,组装的太阳能电池光电转换效率最好。

关 键 词:溶胶-凝胶法  TiO2/ZnTiO3  复合物  钙钛矿太阳能电池  光阳极  光电转换效率

Preparation and Properties of TiO2/ZnTiO3 Composites via a Sol-Gel Route Served as Photoanode of Perovskite Solar Cells
XU Yan,ZHANG Wengjing,HU Mulin.Preparation and Properties of TiO2/ZnTiO3 Composites via a Sol-Gel Route Served as Photoanode of Perovskite Solar Cells[J].Materials Review,2016,30(20):21-25.
Authors:XU Yan  ZHANG Wengjing  HU Mulin
Abstract:TiO2/ZnTiO3 composites with different molar ratios were prepared through a sol-gel route,and the resultant powders′crystal structure was analyzed by XRD.The films which were served as perovskite solar cells′pho-toanode were prepared by silk screen printing and characterized by SEM to observe their surface morphologies,and the cells′properties were also tested.Our experiment and analyses indicated that the molar ratio of Zn/Ti has a great in-fluence to the cells′conversion efficiency,and the cell fabricated using the composite photoanode with n(Zn)∶n(Ti)=1∶6 exhibits the highest photoelectric conversion efficiency.
Keywords:sol-gel method  TiO2/ZnTiO3 composites  perovskite solar cells  photoanode  photoelectric conversion efficiency
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