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Microstructural investigation of the breakdown of the protective oxide scale on a 304 steel in the presence of oxygen and water vapour at 600 °C
Authors:M. Halvarsson  J.E. Tang  J.-E. Svensson
Affiliation:a Department of Applied Physics, Chalmers University of Technology, SE-412 96 Göteborg, Sweden
b Department of Chemistry, Göteborg University, SE-412 96 Göteborg, Sweden
c Department of Environmental Inorganic Chemistry, Chalmers University of Technology, SE-412 96 Göteborg, Sweden
Abstract:This article focuses on the detailed microstructural investigation of the oxide scale formed on a 304 steel in the presence of oxygen and water vapour (40%) at 600 °C. The work has been carried out using a combination of microanalytical techniques including FIB, TEM, EDX and electron diffraction. The local breakdown of the initially protective oxide scale and the growth of island/crater oxide morphology are described. Special consideration is given to the influence of the microstructure of the steel and the oxide scale on the breakdown behaviour.
Keywords:A. Stainless steel   B. TEM   C. Oxidation   FIB   Vaporization
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