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Recent advances in titanium dioxide/graphene photocatalyst materials as potentials of energy generation
Authors:Ephraim M Kiarii  Krishna K Govender  Patrick G Ndungu  Penny P Govender
Affiliation:1.Department of Applied Chemistry,University of Johannesburg,Johannesburg,South Africa;2.Council for Scientific and Industrial Research,Meraka Institute, Centre for High Performance Computing,Cape Town,South Africa
Abstract:The properties of titanium dioxide ((hbox {TiO}_{2}))/graphene/graphene oxides (GO) are examined in this study. These views summarize the recent theoretical and experimental novel approaches in the catalytic activity of (hbox {TiO}_{2})/graphene interface. Imperative results at a level of detail, suitable for upcoming experimental and theoretical researchers involved an overview of the enthralling characteristics of (hbox {TiO}_{2}) and graphene composites were presented. Aspects like crystal lattice, electronic band structure and phonon dispersion, among others that were used to describe the properties of a (hbox {TiO}_{2}) interface with pristine graphene and graphene dioxide among other composites are discussed. In particular, this review covers reactivity, binding energies, geometric structures as well as the photocatalytic activity of anatase (hbox {TiO}_{2}) surfaces with graphene and graphene oxide with hybrid nanocomposites. These views also explore the understanding of the (hbox {TiO}_{2}) interactions with graphene and possible applications. Finally, highlights on the challenges and proposed strategies in developing advanced photocatalytic semiconductor-based composites for water-splitting applications are provided.
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