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微弧氧化生成钛酸盐系铁电薄膜研究
引用本文:黄文波,李文芳,吴晶.微弧氧化生成钛酸盐系铁电薄膜研究[J].材料科学与工艺,2011,19(2):52-56.
作者姓名:黄文波  李文芳  吴晶
作者单位:华南理工大学材料科学与工程学院;华南理工大学材料科学与工程学院;广东交通职业技术学院机电工程系
基金项目:中国博士后科学基金特别资助项目(200902317)
摘    要:为开发新的铁电薄膜制备工艺,需将Ti板微弧氧化.采用Ba(OH)2、Ba(CH3COO)2、BaCl2、Ba(OH)2+Ba(NO3)2及Pb(CH3COO)2对Ti板进行微弧氧化试验,并对生成的薄膜进行物相组成和显微形貌的分析.结果表明:Ti板在BaCl2、Pb(CH3COO)2及Ba(OH)2+Ba(NO3)2中不...

关 键 词:铁电薄膜  制备技术  钛酸盐  BaTiO3  微弧氧化

Deposition of titanate ferroelectric thin films by microarc oxidation
HUANG Wen-bo,LI Wen-fang and WU Jing.Deposition of titanate ferroelectric thin films by microarc oxidation[J].Materials Science and Technology,2011,19(2):52-56.
Authors:HUANG Wen-bo  LI Wen-fang and WU Jing
Affiliation:College of Material Science and Engineering,South China University of Technology,Guangzhou 510640,China;College of Material Science and Engineering,South China University of Technology,Guangzhou 510640,China;Dept.of Mechanical and Electrical Engineering,Guangdong Communication Polytechnic,Guangzhou 510800,China
Abstract:To develop a new technology for deposition of ferroelectric thin film,Ti plates must be microarc oxidated.In this paper,Ti plates were processed by microarc oxidation(MAO) in a series of electrolytes,which were composed of Ba(OH)2,Ba(CH3COO)2,BaCl2,Ba(OH)2+Ba(NO3)2,Pb(CH3COO)2respectively,and the phase composition and morphologies of films were investigated.Results revealed that microarc occurred successfully in Ba(OH)2 and Ba(CH3COO)2 solutions but failed in BaCl2、Pb(CH3COO)2 and Ba(OH)2+Ba(NO3)2 solutions.The film was mainly composed of BaTiO3 phase and scattered with small holes.By comparing the results with different electrolytic,concentrations and currents,a general law for selection of electrolytic compositions and optimal technique was put forward.Dielectric constant of 112 was measured at frequency of 1 kHz.
Keywords:ferroelectric thin film  deposition  titanate  BaTiO3  microarc oxidation
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