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Fibre orientation effect on polypropylene/milled carbon fiber composites in the presence of carbon nanotubes or graphene as a secondary filler: Application on PEM fuel cell bipolar plate
Affiliation:1. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Malaysia;2. Centre for Materials Engineering and Smart Manufacturing, Mechanical Engineering Programme, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Malaysia;3. Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia;1. Department of Industrial Chemistry, Faculty of Science, Chiang Mai University, Muang, Chiang Mai 50200, Thailand;2. Material Science Research Center, Faculty of Science, Chiang Mai University, Muang, Chiang Mai 50200, Thailand;1. Advanced Material Group, Faculty of Mechanical Engineering, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia;2. Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia;1. Central South University, State Key Laboratory of High Performance and Complex Manufacturing, Lushan South Road 932, 410083 Changsha, China;2. Clausthal University of Technology, Institute of Polymer Materials and Plastics Engineering, Agricolastrasse 6, D-38678 Clausthal-Zellerfeld, Germany
Abstract:Conductive polymer composite (CPC) materials are extensively used for the bipolar plate in Polymer Electrolyte Membrane Fuel Cells (PEMFCs). The produced CPC materials through the extrusion process strongly relate to electrical conductivity and mechanical properties. In this study, milled carbon fibre (MCF) reinforced polypropylene (PP) incorporating carbon nanotube (CNT), or graphene nanoplatelets (xGNP) are pre-mixed using the extrusion process to orientate the fibres before undergoing the compression moulding at 13.8 MPa and 200 °C for 15 min. The CNT composites exhibited the higher through-plane conductivity of 14.8 S/cm as compared to xGnP composites with 4.9 S/cm at 70 wt% of MCF. The flexural strength improved after being compressed to 99.6 MPa and 172.5 MPa for 70 wt% of CNT and xGNP, respectively. This reveals that the oriented fibres can boost the CPC performance.
Keywords:Conductive polymer composite  Extrusion  Electrical conductivity  Mechanical properties
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