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Production,performance and cost analysis of anode-supported NiO-YSZ micro-tubular SOFCs
Affiliation:1. Gebze Technical University, Institute of Energy Technologies, TR-41400, Gebze, Kocaeli, Turkey;2. Kocaeli University, Engineering Faculty, Department of Metallurgical and Materials Engineering, TR-41380, Kocaeli, Turkey;3. Gebze Technical University, Faculty of Engineering, Department of Material Science and Engineering, TR-41400, Gebze, Kocaeli, Turkey;1. Department of Mechanical Engineering, University of South Carolina, Columbia, SC 29208, USA;2. Department of Water Quality Engineering, School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, PR China;3. Department of Chemical Engineering, University of South Carolina, Columbia, SC 29208, USA;1. School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China;2. Department of Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China;3. Department of Chemical Engineering, Curtin University, Perth, WA 6845, Australia;1. Union Research Center of Fuel Cell, School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China;2. State Key Laboratory of Power Systems, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China;1. Vestel Defense Industry, Universiteler Mah. Ihsan Dogramaci Bul, Titanyum Blok 17/B Teknokent ODTU, 06800, Ankara, Turkey;2. Nigde Omer Halisdemir University Prof. Dr. T. Nejat Veziroglu Clean Energy Research Center, 51245, Nigde, Turkey;3. Nigde Omer Halisdemir University, Mechanical Engineering Department, 51245, Nigde, Turkey;1. Nigde University Prof. Dr. T. Nejat Veziroglu Clean Energy Research Center, 51245, Nigde, Turkey;2. Recep Tayyip Erdogan University, Mechanical Engineering Department, 53100, Rize, Turkey;3. Duzce University, Mechanical Engineering Department, 81620, Duzce, Turkey;4. Nigde University, Mechanical Engineering Department, 51245, Nigde, Turkey
Abstract:In the present study, the anode-supported micro-tubular solid oxide fuel cells (MT-SOFCs) with an electrolyte thin interlayer were manufactured. The anode support tubes consisting of 56 wt% nickel oxide and 44 wt% YSZ (8 mol% yttria (Y2O3) stabilized zirconia (ZrO2)) were produced by using the thermo-extrusion method, whereas the electrolyte and cathode layers were manufactured using the dip-coating method. The half-cells consisting of anode and electrolyte were manufactured by using two different methods. In the first method, the anode-support tubes were pre-sintered at 1200 °C, then covered with the electrolyte layer by using the dip-coating method and then exposed to second sintering at 1400 °C. In the second method, the anode and electrolyte layers were sintered together at 1400 °C (co-sintering) in order to produce the half-cells. The half-cells that were produced and then coated with cathode solutions by using the dip-coating method and the final cells were successfully produced at the end of the sintering at 1150 °C. The porosity and shrinkage percentage values of these MT-SOFCs differed from each other. The power densities of these cells were tested at 700 °C, 750 °C, and 800 °C by using H2 gas as fuel and the results of the microstructural and cost analyses were compared.
Keywords:Anode-supported micro-tubular SOFC  Performance analysis  Thermoplastic extrusion  Dip-coating  Manufacturing cost
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