Cold-rolled magnesium hydride strips decorated with cold-sprayed Ni powders for solid-state-hydrogen storage |
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Affiliation: | 1. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China;2. Institute of Advanced Wear & Corrosion Resistance and Functional Materials, Jinan University, Guangzhou 510632, China;4. Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan;5. Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing Tech University, Nanjing 210009, China |
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Abstract: | The present work reports for the first time application of cold spray coating for doping plastically deformed Mg-strips by different concentrations of fine Ni powders. For present study, Mg rods were cold-rolled for 300 passes and then coated by Ni fine powders, using a cold spray process operated at 150 °C under high argon gas pressure. The Ni powders were pelted into Mg-substrate through the high-velocity jet at a speed of 500 m/s. Under these preparation conditions, Ni powders were plastically deformed at the surface of Mg strips to create numerous pores and cavities, worked as hydrogen diffusion gateway. The as-coated Mg sheets with 3-Ni layers (5.28 wt%) possessed good hydrogenation/dehydrogenation kinetics, implied by a short absorption/desorption time (5.1/11 min) of 6.1 wt% hydrogen at 150 °C/10 bar and 200 °C/200 mbar, respectively. The fabricated solid-state hydrogen storage nanocomposite strips revealed good cyclability of achieving 600 cycles at 200 °C without failure of degradation. |
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Keywords: | Severe plastic deformation Cold-spray technology Catalyzation De/rehydrogenation kinetics Cycle-life-time |
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