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Co-generation of hydrogen and electricity from biodiesel process effluents
Affiliation:1. Department of Automotive Science, Graduate School of Integrated Frontier Sciences, Kyushu University, Nishiku, Fukuoka, 819-0395, Japan;2. Department of Earth Resources Engineering, Graduate School of Engineering, Kyushu University, Nishiku, Fukuoka, 819-0395, Japan;1. Graduate School of Natural and Applied Sciences, Gazi University, 06500, Teknikokullar, Ankara, Turkey;2. Department of Physics, Faculty of Sciences, Gazi University, 06500, Teknikokullar, Ankara, Turkey;1. Biological Process Laboratory, São Carlos School of Engineering, University of São Paulo, Environmental Engineering, Bloco 4-F, Av. João Dagnone, 1100, Santa Angelina, 13563-120, São Carlos, SP, Brazil;2. Marine Institute, Federal University of São Paulo, Rua Dr. Carvalho de Mendonça 144, 11070-102, Santos, SP, Brazil;3. Center of Biological Sciences, Federal University of Santa Catarina, Campus Reitor João David Ferreira Lima, Bairro Trindade, 88040-900, Florianópolis, SC, Brazil;4. Department of Soil Science, “Luiz de Queiroz” College of Agriculture, University of São Paulo, 13418-900, Piracicaba, SP, Brazil;5. Deltares, Daltonlaan 600, 3584 BK Utrecht, the Netherlands;6. Department of Environmental Technology, Wageningen University and Research, P.O. Box 17, 6700 AA, Wageningen, the Netherlands;1. School of Electric Power, North China University of Water Resources and Electric Power, Zhengzhou 450045, China;2. Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education, Chongqing 400044, China;3. School of Environmental and Municipal Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450045, China
Abstract:In this study, we apply a short-term voltage (0.2–0.8 V) to both crude glycerol (CG) and an anaerobic digestion (AD) effluent in a single-chamber microbial fuel cell (MFC) for power production. This improves the bioelectrogenesis in both CG (in MFC-1) and the AD effluent (in MFC-2), but higher power generation is attained in MFC-2. The use of domestic and synthetic wastewaters in the AD process leads to the generation of 195 and 350 mL H2/L-medium, respectively. MFC-2 performs better than MFC-1 in terms of both voltage generation and chemical oxygen demand (COD) reduction. The application of 0.8 V yields a power density of 311 mW/m2 (1.94 times higher than that of the control (160 mW/m2)). In addition, MFC-2 exhibits a 70% COD removal at 0.8 V, which decreases to 56% at 0.2 V. Thus, the application of a short-term voltage in MFC can stimulate both bioelectrogenesis and COD removal.
Keywords:Voltage supplementation  Microbial fuel cells  Crude glycerol  Dark fermentation  Cyclic voltammetry  CG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0040"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Crude glycerol  MFCs"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0050"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Microbial Fuel cells  Hydrogen  COD"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0070"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Chemical oxygen demand  CV"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0080"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Cyclic voltammetry  EIS"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0090"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Electrochemical impedance spectroscopy  VFAs"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0100"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Volatile fatty acids  AD"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0110"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Anaerobic digestion  PD"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0120"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Power density  DC"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0130"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Direct current  NE"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0140"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Net energy  PBS"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0150"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Phosphate buffer solution  DW"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0160"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Domestic wastewater  SW"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0170"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Synthetic wastewater  PW"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0180"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Petroleum wastewater  I"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0190"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Current  V"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0200"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Voltage  W"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0210"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Power  Ω"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0220"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Resistance  Ohmic resistance  Charge transfer resistance  Internal resistance
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