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Using chemical looping gasification with Fe2O3/Al2O3 oxygen carrier to produce syngas (H2+CO) from rice straw
Affiliation:1. Collaborative Innovation Center of Biomass Energy, Henan Agricultural University, Zhengzhou, Henan Province, 450002, China;2. Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei, 10607, Taiwan;3. Department of Chemical Engineering, National Taiwan University, Taipei, 10617, Taiwan;1. Key Laboratory of Renewable Energy, Chinese Academy of Sciences (CAS), Guangzhou Institute of Energy Conversion, CAS, China;2. Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, CAS, China;3. Thermal & Environmental Engineering Institute, Tongji University, China;4. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, China;5. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, China;1. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China;2. School of Energy and Power Engineering, Nanjing Institute of Technology, Nanjing 211167, China;1. Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;1. National Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, China;2. State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206, China
Abstract:The chemical looping gasification of rice straw using Fe2O3/Al2O3 as oxygen carrier was studied at reaction time of 5–25 min, steam-to-biomass (S/B) ratio of 2.0–4.8, reaction temperature of 750–950 °C, and oxygen carrier-to-biomass of 1.0. The gasification can be regarded completed in 20-min reaction. There exist an optimal S/B ratio of 2.8 and reaction temperature of 900 °C leading to maximum performances yielded are 1.22 Nm3/kg gas yield at 54.6% H2+24.2% CO. The studied Fe2O3 oxygen carrier/rice straw is a feasible platform for syngas production from an agricultural waste.
Keywords:Biohydrogen  Chemical looping gasification  Hydrogen yield  Oxygen carrier
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