首页 | 本学科首页   官方微博 | 高级检索  
     


1T/2H MoS2/MoO3 hybrid assembles with glycine as highly efficient and stable electrocatalyst for water splitting
Affiliation:1. Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, Hunan, China;2. Songshan Lake Materials Laboratory Dongguan, Guangdong 523808, China;3. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
Abstract:Despite great efforts have been made during the past decade to improve the efficiency of hydrogen evolution reaction (HER) onto the MoS2-based electrocatalysts via increasing the number of active sites, further improvements are crucial to avoid the detachment of 2D MoS2 nanosheets from the substrate during the long-term water splitting under intense HER. In this study, we report on the formation of highly efficient and surprisingly stable layer composed of 2D nanoplatelets from the hybrid-type MoS2 as a new prospective electrocatalyst for HER from acidic water solution. This layer was formed via one-pot hydrothermal synthesis in the solution containing ammonium heptamolybdate, thiourea and glycine (Gly). The products obtained were characterized by SEM, HRTEM, XRD, Raman, XPS, and potential cycling. Note that at the designed hybrid-type MoS2/MoO3-Gly nanoplatelets the HER rate can achieve a stable electrochemical performance for days with ~100 mA cm?2 current density at ?0.35 V potential vs RHE.
Keywords:Hydrogen evolution reaction  Water splitting  Molybdenum disulfide  Hybrid electrocatalyst
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号