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Solar-driven novel methane reforming with carbon looping for hydrogen production
Affiliation:1. School of Mechatronics Engineering, Harbin Institute of Technology, 92, West Dazhi Street, Harbin 150001, PR China;2. School of Energy and Power Engineering, Northeast Electric Power University, 169, Changchun Street, Jilin 132012, PR China;3. School of Automobile Engineering, Harbin Institute of Technology at Weihai, 2, West Wenhua Road, Weihai 264209, PR China;1. Physics & Engineering Department, Taylor University, 236 W. Reade Ave, Upland, IN 46989, United States;2. Department of Mechanical Engineering, University of Minnesota, 111 Church St. S.E., Minneapolis, MN 55455, United States;1. School of Mechatronics Engineering, Harbin Institute of Technology, 92, West Dazhi Street, Harbin 150001, PR China;2. School of Energy and Power Engineering, Northeast Electric Power University, 169, Changchun Street, Jilin 132012, PR China;3. School of Automobile Engineering, Harbin Institute of Technology at Weihai, 2, West Wenhua Road, Weihai 264209, PR China;4. School of Chemical Engineering, Northeast Electric Power University, 169, Changchun Street, Jilin 132012, PR China;5. Department of Architecture and Built Enviroment, University of Nottingham, NG7 2RD, UK;1. School of Automobile Engineering, Harbin Institute of Technology at Weihai, 2, West Wenhua Road, Weihai 264209, PR China;2. Department of Mechanical Engineering, University of Tulsa, 800, South Tucker Road, OK 74104, USA;1. School of Mechatronics Engineering, Harbin Institute of Technology, 92, West Dazhi Street, Harbin 150001, PR China;2. School of Energy and Power Engineering, Northeast Electric Power University, 169, Changchun Street, Jilin 132012, PR China;3. School of Automobile Engineering, Harbin Institute of Technology at Weihai, 2, West Wenhua Road, Weihai 264209, PR China;4. School of Chemical Engineering, Northeast Electric Power University, 169, Changchun Street, Jilin 132012, PR China;5. Department of Architecture and Built Enviroment, University of Nottingham, NG7 2RD, UK;1. Deutsches Zentrum für Luft-und Raumfahrt, Solar Research, Karl-Heinz-Beckurts-Str.13, 52428 Jülich, Germany;2. Deutsches Zentrum für Luft-und Raumfahrt, Solar Research, Linder Höhe, 51147 Köln, Germany
Abstract:As a renewable source, solar energy plays an important role in meeting energy demand for human beings and in relieving global warming. In this paper, the concentrated solar heat is utilized to drive the high-endothermic methane reforming with carbon looping. In so doing, the process increases the utilization of CO2 and reduces the carbon emissions as well as saves the extra fuel consumption for combustion, leading to high efficiency of energy utilization. By optimizing this proposed system, the energy efficiency can reach approximate 67.13% with simultaneously reducing CO2 emissions by 34.98% compared with SMR process. Exergy analysis is used to assess the location of irreversibility within process. The maximal part of exergy destroyer was localized in reformer with a contribution of 68%. In addition, the effects of hourly variation of direct normal irradiation on thermodynamic performance and methane conversion on the four typical days (spring equinox, summer solstice, autumn equinox, winter solstice) were analyzed in this work. The current work might be insightful for solar-hydrogen production field.
Keywords:Solar energy  Methane reforming  Carbon looping  Hydrogen production
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