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PEM water electrolysis: Innovative approaches towards catalyst separation,recovery and recycling
Affiliation:1. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, IEK-3: Electrochemical Process Engineering, 52425 Jülich, Germany;2. Chair for Fuel Cells, RWTH Aachen University, Germany;1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, 30 College Road, Beijing 100083, China;2. Department of Physical Chemistry, University of Science and Technology Beijing, 30 College Road, Beijing 100083, China;3. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Science, 72 Wenhua Road, Shenyang 110016, China;1. Univ Grenoble-Alpes, CNRS, LEPMI, F-38000, Grenoble, France;2. Univ Grenoble-Alpes, CNRS, GSCOP, F-38000, Grenoble, France;3. Réseau sur le Stockage Electrochimique de l''Energie (RS2E), FR CNRS 3459, France;4. UMR CNRS 5600 EVS Ecole des Mines de Saint-Etienne, I. Fayol, 158, Cours Fauriel, Saint-Etienne, F42023, France;1. IC2MP UMR CNRS 7285, “Equipe SAMCat”, Université de Poitiers, 4 rue Michel Brunet B27, BP 633, 86022 Poitiers cedex, France;2. CEA, LITEN, DEHT/LCPEM, 17 rue des Martyrs, F-38054 Grenoble, France;3. HELION Hydrogen Power, Domaine du Petit Arbois, Bâtiment Jules Verne, BP 71, 13545 Aix en Provence, France;1. Fuel Cell System and Engineering Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, 116023, China;2. Graduate University of Chinese Academy of Sciences, Beijing, 100049, China;1. Department of Chemical Engineering Education, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, Republic of Korea;2. Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, Republic of Korea;3. Hydrogen Research Department, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon, 34129, Republic of Korea;1. Key Laboratory of Renewable Energy, Guangzhou Institution of Energy Conversion, Chinese Academy of Sciences, Guangdong, 510640, China;2. Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institution of Energy Conversion, Chinese Academy of Sciences, Guangdong, 510640, China
Abstract:We report the development of a facile recycling process for catalyst coated membranes (CCMs) used in polymer electrolyte membrane (PEM) water electrolyzers. After performance evaluation in an assembled electrolysis cell, ultrasonication is used to provide high-yield recovery of not only the noble-metal catalyst materials, but also of the fluoropolymer membrane itself, without the release of hazardous gases. Transmission electron microscopy (TEM) and electrochemical characterization are used to confirm the retention of catalyst particle size, and of the performance of the recycled CCMs. Furthermore, our projections indicate that, if this approach is widely employed, existing resources of noble metals will prove sufficient for the gigawatt-scale implementation of PEM water electrolyzers. This has profound implications for the achievement of current targets for reducing the consumption of precious metals for applications in electrolyzers, fuel cells and other energy storage devices.
Keywords:Iridium  Platinum  Recycling  PEM water electrolyzers  Hydrogen  Market penetration
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