Hydrogen production of bio-oil steam reforming combining heat recovery of blast furnace slag: Thermodynamic analysis |
| |
| Affiliation: | 1. Department of Biotechnology, MNNIT Allahabad, Prayagraj, 211004, U.P, India;2. Department of Chemistry, MNNIT Allahabad, Prayagraj, 211004, U.P, India;1. Department of Chemistry, Guru Nanak Khalsa College, Nathalal Parekh Road, Matunga, Mumbai 400019, India;2. Department of Chemical Engineering, Institute of Chemical Technology, Nathalal Parekh Road, Matunga, Mumbai 400019, India;1. Faculty of Engineering and Applied Science, University of Ontario Institute of Technology, 2000 Simcoe Street North, Oshawa, Ontario, L1H 7K4, Canada;2. Faculty of Engineering and Applied Science, Memorial University of Newfoundland, 240 Prince Phillip Drive St. John''s, Newfoundland and Labrador, A1B 3X5, Canada;1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Chongqing 400030, China;2. Institute of Engineering Thermophysics, Chongqing University, Chongqing 400030, China;1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Chongqing 400030, China;2. Institute of Engineering Thermophysics, Chongqing University, Chongqing 400030, China |
| |
| Abstract: | Hydrogen production via steam reforming of bio-oil combining heat recovery of blast furnace slag was investigated via thermodynamic analysis in this paper. The addition of blast furnace slag just had a slight enhancement for hydrogen production from the steam reforming process of bio-oil at low temperature, and had almost no thermodynamic effect (either promotion or restraint) for the steam reforming reaction equilibrium at high temperature where higher H2 yield were obtained, no matter how much blast furnace slag was added. However, different masses of blast furnace slag as heat carrier supply different amounts of heat, so the optimal blast furnace slag addition was performed via energy balance. If the sensible heats of the reformed gas and the slag after steam reforming reactions were unrecycled, the required mass of blast furnace slag was over 30 times of bio-oil mass, while the required slag mass was just 11.5 times of bio-oil mass if the sensible heats after the steam reforming reactions were recycled. For the latter, about 0.144 Nm3 H2 per kg blast furnace slag was obtained at the reforming temperature of 700–750 °C and the steam/carbon mole ratio of 6. |
| |
| Keywords: | Bio-oil Hydrogen production Steam reforming Blast furnace slag Waste heat recovery |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
