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Auto-combustion synthesis,structural analysis,and electrochemical solid-state hydrogen storage performance of strontium cobalt oxide nanostructures
Affiliation:1. Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, P.O. Box 87317-51167, Iran;2. Environmental Technology Division, School of Industrial Technology, Universiti Sains Malaysia, 11800, Minden, Penang, Malaysia;3. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Viet Nam;1. Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P. O. Box 87317-51167, Iran;2. Department of Chemistry, College of Science, University of Hormozgan, Bandar Abbas 71961, Iran;1. Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran;2. Department of Physic, Faculty of Science, Islamic Azad University-Qom Branch, Qom, Iran;3. Faculty of Physics, University of Kashan, Kashan, Iran;4. Department of Chemistry, Faculty of Science, Payam Noor University, Iran
Abstract:Hydrogen storage in transition mixed metal oxides (MMOs) are predicted from their tendency for adsorption-desorption hydrogen. Hydrogen itself requires initial forces pressure for initiation of condensation. MMOs, based on their effective immobilization matrices, are potential nanocatalysts for energy storage. Even various materials are highlighted for hydrogen storage; however, their adsorption capacities are insufficient for real applications. Here we report, for the first time, a novel hydrogen storage MMOs (Sr2Co9O14 nanoparticles) potential for physical hydrogen sorption, containing a redox species. This polycrystalline nanoparticle is prepared via a combustion method in the presence of various fuels like glucose, fructose, sucrose, lactose, and maltose. The glucose supports the pure and homogenous formation of Sr2Co9O14 nanoparticles consisting the particles less than 100 nm. Interestingly, a maximum discharge capacity of around 950 mA h/g at room temperature has recorded; emphasizing Sr2Co9O14 nanoparticles is a potential substrate for hydrogen storage.
Keywords:Nanostructures  Energy  Hydrogen storage  Mixed metal oxides
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