Ozonolysis of 1-phenylazo-2-naphthol |
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Authors: | Masaki Matsui Katsuyoshi Shibata Yoshimi Takase |
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Affiliation: | Department of Industrial Chemistry, University of Gifu, Yanagido, Gifu, 501-11 Japan |
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Abstract: | The ozonolysis of 1-phenylazo-2-naphthol was studied using ozone in an oxygen stream. 1-Phenylazo-2-naphthol reacts with ozone to give benzene, chlorobenzene, phenol, o-naphthoquinone, phthalide and phthalic anhydride. The mechanism of the reaction is explained as an electrophilic attack of ozone with the hydrazone tautomer of 1-phenylazo-2-naphthol. |
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