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Influence of normal stress difference on polymer drop deformation
Authors:Leon Levitt  Christopher W. Macosko  Scott D. Pearson
Abstract:Polypropylene drops of varying viscosity and elasticity were sheared in a polystyrene matrix. Two transparent, counter-rotating parallel disks provided simple shear flow. By adjusting the speed of one disk the drop center was fixed in the laboratory frame and deformation followed via high magnification video camera. It was found that with high matrix elasticity drops of the minor phase stretched perpendicular (x3) to the flow direction (x1). This is the first report of widening of drops in shear flow. An analytical relation was established between the second normal stress differences of the phases and degree of widening. The formation of sheets and the phenomena of widening results in a larger than affine area generation.
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