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Synthesis and Characteristics of Dodecyl Isopropylolamine and Derived Surfactants
Authors:Ziyafaddin H. Asadov  Ravan A. Rahimov  Khuraman A. Mammadova  Atash V. Gurbanov  Gulnara A. Ahmadova
Affiliation:1. Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Hojaly ave. 30, 1025, Baku, Azerbaijan
2. Baku State University, Z. Khalilov st. 23, 1148, Baku, Azerbaijan
Abstract:Dodecyl isopropylolamine has been synthesized on the basis of dodecylamine and propylene oxide. The structure of dodecyl isopropanolamine has been determined by X‐ray diffraction, elemental analysis, IR‐ and NMR‐spectroscopic methods. Ionic surfactants have been synthesized by interaction of dodecyl isopropylolamine with various acids (HCl, HBr, acetic and propionic) and alkyl halides (methyl iodide, ethyl bromide and n‐propyl bromide). Colloidal‐chemical parameters, petroleum‐collecting and petroleum dispersing capacities of the synthesized cationic surfactants have been studied.
Keywords:Amine  Surfactant  Surface tension  Micellization  Adsorption  Counterion  Petroleum‐collecting
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