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Synthesis,Surface and Antimicrobial Activities of Cationic Gemini Surfactants with Semi-Rigid Spacers
Authors:Hai-lin Zhu  Zhi-yong Hu  Xue-mei Ma  Jian-long Wang  Duan-lin Cao
Affiliation:1.School of Chemical Engineering and Environment,North University of China,Taiyuan,People’s Republic of China
Abstract:Four cationic gemini surfactants featuring semi-rigid spacers were synthesized via a two-step process. The surface-active properties of these surfactants were investigated through surface tension and electrical conductivity measurement. The thermodynamic parameters of micellization were evaluated from electrical conductivity measurements at temperatures ranging from 293 to 313 K. The aggregation behavior of these synthesized gemini surfactants in water were investigated using dynamic light scattering and transmission electron microscopy. Further, the antimicrobial activities of these synthesized gemini surfactants against both Gram-positive and Gram-negative bacteria were also investigated.
Keywords:Gemini surfactants  Semi‐rigid spacer  Critical micelle concentration  Thermodynamic parameter  Aggregation behavior  Antimicrobial activity
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