Synthesis,Surface Properties and Effect of an Amino Acid Head Group of 11-(2-Methoxy-4-vinylphenoxy)undecanoicacid-Based Anionic Surfactants |
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Authors: | Prabhakara Rao Darapureddi Rati Ranjan Nayak |
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Affiliation: | 1.Centre for Lipid Research,CSIR-Indian Institute of Chemical Technology,Hyderabad,India |
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Abstract: | Our present research describes the surface properties of three biobased anionic surfactant synthesized from vinylguaiacol and 11-bromo undecanoic acid. To further improve its hydrophobicity and bioavailability, amino acid head group incorporation was carried out. All these synthesized compounds were thoroughly characterized using NMR and mass spectroscopy. The performance properties such as foaming, wetting, emulsification value and calcium tolerance were evaluated. The studied surfactants possess excellent emulsion stability and moderate calcium tolerance as compared to commercially available surfactant sodium lauryl sulfate (SLS). The micelle formation and the thermodynamics involved at the air–water interface were estimated from surface tension measurements. These surfactants showed a higher tendency towards adsorption at the air–water interface than micellization. Dynamic light scattering and steady state fluorescence anisotropy study were carried out to shed light on the bulk micellization properties of the synthesized surfactant. Along with spherical micelles of <5 nm size, larger aggregates (35–84 nm) were observed with higher anisotropy values. FESEM images further confirmed the larger spherical micelles formed by these surfactants. The surfactants formed chiral aggregates above the critical micelle concentration as indicated by circular dichroism spectra. These surfactants may be suitable candidates for additives to detergents to improve their calcium tolerance especially in the case of hard water. Furthermore, a low foaming ability along with high emulsion stability may find these surfactants to be better replacement of the conventional surfactant used as emulsifiers in many industrial applications. |
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Keywords: | Vinylguaiacol Undecanoic acid Amino acid Surface activity Surface tension Micellization Dynamic light scattering Anisotropy |
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