Crystal structure and magnetic properties of the new ternary actinide compounds AnPd5Al2 (An = U, Np) |
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Authors: | Y Haga D Aoki Y Homma S Ikeda TD Matsuda E Yamamoto H Sakai N Tateiwa ND Dung A Nakamura Y Shiokawa Y nuki |
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Affiliation: | aAdvanced Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195, Japan;bInstitute for Materials Science, Tohoku University, Oarai, Ibaraki 311-1313, Japan;cGraduate School of Science, Osaka University, Toyonaka 560-0043, Japan |
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Abstract: | We report the crystal structure and magnetic properties of new ternary actinide compounds UPd5Al2 and NpPd5Al2. Both compounds crystallize in the body-centered tetragonal ZrNi2Al5-type tetragonal structure (I 4/mmm). Although the magnetic susceptibility of both compounds follows the Curie–Weiss behavior at high temperature, no magnetic phase transition was observed. UPd5Al2 has a nonmagnetic ground state where the magnetic susceptibility saturates at low temperature, while NpPd5Al2 superconducts below 4.9 K as reported recently. |
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Keywords: | Actinide intermetallics Crystal growth X-ray diffraction |
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