Cationic polymerization initiated by intercalation compounds of Lewis acids |
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Authors: | Iliya Rashkov Ivan Gitsov Ivan Panayotov |
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Affiliation: | 1. Central Laboratory for Polymers, Bulgarian Academy of Sciences, 1040, Sofia, Bulgaria
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Abstract: | The results of initial studies showing the high activity of intercalation compounds of Lewis acids (C30SbCl5, C77FeCl3, C64AlBr3) as initiators of the cationic polymerization of cyclosiloxanes are presented. The influence of some reaction conditions on the yield and the molecular mass of the polymers formed is described. |
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