| 5-硝基四唑亚铜的合成与表征 |
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| 引用本文： | 蒲彦利,盛涤伦,朱雅红,陈利魁,杨斌,王燕兰,徐珉昊. 5-硝基四唑亚铜的合成与表征[J]. 火工品, 2009, 0(5) |
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| 作者姓名： | 蒲彦利 盛涤伦 朱雅红 陈利魁 杨斌 王燕兰 徐珉昊 |
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| 作者单位： | 中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061;中国兵器工业第213研究所,陕西,西安,710061 |
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| 摘 要： | 以氯化亚铜、5-硝基四唑钠等为原料合成了一种起爆药5-硝基四唑亚铜.利用能谱分析、红外光谱、紫外-可见光谱及元素分析和DSC测试等方法,对5-硝基四唑亚铜进行了结构表征.初步性能研究表明,5-硝基四唑亚铜的初始分解温度为291℃,峰温为324℃,其分解较剧烈,且热稳定性较好;感度测试结果显示,5-硝基四唑亚铜的撞击感度较BNCP钝感,火焰感度比BNCP敏感、比LA钝感.
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| 关 键 词： | 起爆药 5-硝基四唑亚铜 结构 性能 感度 |
Synthesis and Characterization of Copper(I) nitrotetrazolate |
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| PU Yan-li,SHENG Di-lun,ZHU Ya-hong,CHEN Li-kui,YANG Bin,WANG Yan-lan,XU Min-hao. Synthesis and Characterization of Copper(I) nitrotetrazolate[J]. Initiators & Pyrotechnics, 2009, 0(5) |
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| Authors: | PU Yan-li SHENG Di-lun ZHU Ya-hong CHEN Li-kui YANG Bin WANG Yan-lan XU Min-hao |
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| Abstract: | Copper(I) nitrotetrazolate(CuNT) was synthesized from cuprous chloride and sodium 5-nitrotetrazolate.The products was characterized by energy dispersive spectroscopyJR,UV,elemental analysis and thermal analysis methods.The explosive property was also studied.The results show that,the initial decomposition temperature of CuNT is 291℃,the temperature peak value is 324℃,the process of thermal decomposition is severe,and the thermal stability of CuNT is good. Compared to BNCP,CuNT is more insensitive to impact and sensitive to flame,while it is more insensitive to flame than LA. |
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| Keywords: | Primary explosive Copper(I) nitrotetrazolate Structure Property Sensitivity |
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