| Structure and Fluorescence Emission of Hetero-Nuclear Complexes of Europium-Lanthanum Nitrates with N,N′-Substituted Adipamide |
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| 引用本文： | 徐庆锋,戴洁,周家宏,张道,刘全成,郁开北.Structure and Fluorescence Emission of Hetero-Nuclear Complexes of Europium-Lanthanum Nitrates with N,N′-Substituted Adipamide[J].中国稀土学报(英文版),2002,20(2). |
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| 作者姓名： | 徐庆锋 戴洁 周家宏 张道 刘全成 郁开北 |
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| 作者单位： | 1. Department of Chemistry，Suzhou University，Suzhou 215006，China; 2. Department of Chemistry，Nanjing Normal University，Nanjing 210008，China; 3. Chengdu Center of Analysi |
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| 基金项目： | ProjectsupportedbytheKeyLaboratoryofOrganicSynthesis，JiangsuProvince (T2 10 90 5 3 ) |
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| 摘 要： | Ｌｕｍｉｎｅｓｃｅｎｔｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｅｓｈａｖｅｂｅｅｎｉｎｔｅｎｓｉｖｅｌｙｓｔｕｄｉｅｄｆｏｒｔｈｅｉｒｗｉｄｅａｐｐｌｉｃａ ｔｉｏｎｓｉｎｐｈｏｔｏ ｄｅｖｉｃｅｓａｎｄｆｌｕｏｒｏ ａｎａｌｙｓｉｓ ,ｅｓ ｐｅｃｉａｌｌｙｉｎｔｈｅｕｓｅａｓｌｕｍｉｎｅｓｃｅｎｔｌａｂｅｌｓｉｎｆｌｕ ｏｒｏ ｉｍｍｕｎｏａｓｓａｙｆｉｅｌｄ1] .Ｓｉｎｃｅｔｈｅｂａｃｋ ｇｒｏｕｎｄｌｕｍｉｎｅｓｃｅｎｃｅｏｆｂｉｏｌｏｇｉｃａｌｍａｔｅｒｉａｌｓｉｓｕｓｕａｌｌｙｓｈｏｒｔ ｌｉｖｅｄ…
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Structure and Fluorescence Emission of Hetero-Nuclear Complexes of Europium-Lanthanum Nitrates with N,N′-Substituted Adipamide |
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| Xu Qingfeng,Dai Jie,Zhou Jiahong,Zhang Dao,Liu Quancheng,Yu Kaibei.Structure and Fluorescence Emission of Hetero-Nuclear Complexes of Europium-Lanthanum Nitrates with N,N′-Substituted Adipamide[J].Journal of Rare Earths,2002,20(2). |
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| Authors: | Xu Qingfeng Dai Jie Zhou Jiahong Zhang Dao Liu Quancheng Yu Kaibei |
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| Abstract: | A europium-lanthanum hetero-nuclear complex with new ligand N, N′-dimethyl-N, N′-diphenyladipamide (MPAA) was prepared. The one dimensional chain structure of La0.5Eu0.5(MPAA)2(NO3)3] was determined crystallographicaly. The europium ion and lanthanum ion statistically lie at the position of the metal ion with M=1/2(La+Eu). Each Ln3+ ion is nine-coordinated including three bidentate nitrates, three carboxyl groups from three MPAA molecules, in which two MPAA are act as bridge ligand. The intensity of fluorescence of La3+-Eu3+ heteronuclear complex A was obviously higher than that of pure Eu3+ complex B both in solution and in solid state. |
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| Keywords: | rare earths europium lanthanum heteronuclear complex fluorescence |
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