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Synthesis and Application of Lanthanide Complexes with Schiff Base of Pridoxylidence-Glycine
作者姓名:黄晓华  周青  王玉红  王云翔  李奚  王小锋  李邨
作者单位:Southern Yangtze University,Nanjing Normal University,Suzhou Railway Teachers College,Suzhou Railway Teachers College,Nanjing Normal University,Nanjing Normal University,Nanjing Normal University Wuxi 214036,China,Nanjing Normal University,Nanjing 210024,China,Nanjing 210024,China,The Key Laboratory of Industrial Biotechnology,Ministry of Education,Wuxi 214036,China,Suzhou 215009,China,Suzhou 215009,China,Nanjing 210024,China,Nanjing 210024,China,Nanjing 210024,China
基金项目:KeyLaboratoryofAgo ProductpollutionControlofMOA(KF 2 0 0 1 1),FoundationofStatePlanningCommission(GJX0 110 0 6 2 6 ) ,NatureScienceFoundationofHighEducationofJiangsu ( 01KJB15 0 0 0 6)andKeyLaboratoryofNanjingNormalUniversity (K0 0 10 2 5 )
摘    要:Theharmfulnessofheavymetalelementsonplantsisoneoftheseriousenvironmentalproblemsofthemodernworld .Inrecentyears ,thestudyonthemisalsooneofveryac tiveresearchprojectsinplantpollutionecologyfields1~ 6 ] .LanthanidecomplexeswiththeSchiffbaseareaclassofcompou…

关 键 词:西夫碱  IR  H-NMR  UV  缓和效应  稀土  甘氨酸

Synthesis and Application of Lanthanide Complexes with Schiff Base of Pridoxylidence-Glycine
Huang Xiaohua,Zhou Qing,Wang Yuhong,Wang Yunxiang,Li Xi,Wang Xiaofeng,Li Chun.Synthesis and Application of Lanthanide Complexes with Schiff Base of Pridoxylidence-Glycine[J].Journal of Rare Earths,2002,20(6):646-650.
Authors:Huang Xiaohua  Zhou Qing  Wang Yuhong  Wang Yunxiang  Li Xi  Wang Xiaofeng  Li Chun
Abstract:A series of novel rare earths complexes with Schiff base of pridoxylidence-glycine acid (HL) were synthesized in absolute methanol under argon atmosphere. The complexes were characterized by elemental analysis, molar conductivity, IR, UV spectra, and H-NMR spectra et al. Data indicate that the complexes have a general formula Ln LCl2*3H2O (Ln=La, Y, Sm, Gd, Dy, Yb; L=C10H11N2O4). Effects of the complexes (Ln=La) on physiological and biochemical indexes of plants under Pb stress were studied. The experiments shown that the complexes obviously mitigated Pb pollution results in decreasing of chlorophyll content, rising of cell membrane permeability, changing catalase(CAT) and distribution of Pb.
Keywords:rare earths  lanthanide complexes  Schiff base  Glycine max seedlings Pb stress  mitigative effect
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