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Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and Phenanthroline Ligands
作者姓名:朱龙观  肖洪平
作者单位:DepartmentofChemistry,ZhefiangUniversity,Hangzhou310027,China
基金项目:ProjectsupportedbytheNationalNaturalFoundationofChina ( 50 0 73 0 1 9)
摘    要:A series of novel quaternary mixed anion complexes of lanthanide containing 1, 10-phenanthroline (phen) and chloroacetate ligands were synthesized from the water/ethanol solution with slightly acidic solution and characterized by elemental analysis, IR, UV and thermal analysis. The EPR and fluorescence properties also were studied.

关 键 词:电子顺磁共振  荧光性能  合成  稀土复合物  光谱分析  邻二氮杂菲  氯代醋酸盐

Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and Phenanthroline Ligands
Zhu Longguan,Xiao Hongping.Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and Phenanthroline Ligands[J].Journal of Rare Earths,2002,20(5):400-403.
Authors:Zhu Longguan  Xiao Hongping
Abstract:A series of novel quaternary mixed anion complexes of lanthanide containing 1,10 phenanthroline (phen) and chloroacetate ligands were synthesized from the water/ethanol solution with slightly acidic solution and characterized by elemental analysis, IR, UV and thermal analysis. The EPR and fluorescence properties also were studied.
Keywords:rare earths  crystal structure  quaternary complex  phenanthroline  chloroacetate
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