| Thermal Decomposition Mechanism and Non Isothermal Kinetics of Complex of [La_2(P-MBA)_6(PHEN)_2]2H_2O |
| |
| 作者姓名： | 张建军 王瑞芬 白继海 王淑萍 |
| |
| 作者单位： | 1. Experimental Center，Hebei Normal University，Shijiazhuang 050016，China; 2. Department of Chemistry，Hebei Normal University，Shijiazhuang 050016，China; 3. Department of Computer，Hebei Teachers′ College of Occupation Technology，Changli，China |
| |
| 基金项目： | ProjectsupportedbytheNaturalScienceFoundationofHebeiProvince ( 2 0 2 1 4 0 )andHebeiEducationDepartment
( 2 0 0 1 1 2 1 ) |
| |
| 摘 要： | Ｏｗｉｎｇｔｏｔｈｅｖａｒｉａｔｉｏｎｏｆｃｏｏｒｄｉｎａｔｅｄｍｏｄｅｓｆｏｒｃａｒｂｏｘｙｌａｔｅａｎｉｏｎｓ ,ｍａｎｙｄｉｆｆｅｒｅｎｔｔｙｐｅｓｏｆｃｒｙｓｔａｌｓｔｒｕｃｔｕｒｅｓｆｏｒｔｈｅｒａｒｅｅａｒｔｈｃｏｍｐｌｅｘｅｓｗｉｔｈａｒｏｍａｔｉｃａｃｉｄａｎｄｎｉｔｒｏｇｅｎ ｃｏｎｔａｉｎｉｎｇｌｉｇａｎｄｓｗｅｒｅｏｂｔａｉｎｅｄ1～ 4 ] .Ｔｈｅｉｒｔｈｅｒｍａｌｄｅｃｏｍｐｏｓｉｔｉｏｎｂｅｈａｖｉｏｒｈａｄｂｅｅｎｒｅ ｐｏｒｔｅｄｉｎｐｒｅｖｉｏｕｓｐａｐｅｒｓ5～ 8] .…
|
Thermal Decomposition Mechanism and Non-Isothermal Kinetics of Complex of [La2(P-MBA)6(PHEN)2]2H2O |
| |
| Zhang Jianjun,Wang Ruifen,Bai Jihai,Wang Shuping.Thermal Decomposition Mechanism and Non Isothermal Kinetics of Complex of [La_2(P-MBA)_6(PHEN)_2]2H_2O[J].Journal of Rare Earths,2002,20(5). |
| |
| Authors: | Zhang Jianjun Wang Ruifen Bai Jihai Wang Shuping |
| |
| Abstract: | The complex of La2(P-MBA)6(PHEN)2]2H2O (P-MBA: p-methylbenzoate and PHEN: 1,10-phenanthroline) was prepared and characterized by elemental analysis and IR spectroscopy. The thermal behavior of La2(P-MBA)6(PHEN)2]2H2O in dynamic nitrogen atmosphere was investigated by TG-DTG techniques. The results show that the thermal decomposition process of the La2(P-MBA)6(PHEN)2]2H2O occurs in five steps. The empirical kinetic model for the first-step thermal decomposition obtained by Malek method is SB(m,n). The activation energy E and the pre-exponential factor lnA for this step reaction are 76.4 kJ*mol-1 and 24.92, respectively. |
| |
| Keywords: | rare earths lanthanum complex non isothermal kinetics P methylbenzoic acid thermal decomposition TG DTG |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
