| Synthesis and Characterization of Rare Earth Complexes of Ferrocenylcarbonylhydrazine |
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| 作者姓名： | 边占喜 董彬 李保国 |
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| 作者单位： | College of Chemistry and Chemical Engineering，Inner Mongolia University，Huhhot 010021，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina( 2 96 6 2 0 0 3 ) |
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| 摘 要： | Ｔｈｅｍｅｔａｌｃｏｍｐｌｅｘｅｓｏｆｈｙｄｒａｚｉｄｅｓｈａｖｅａｔｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅｉｎｔｅｒｅｓｔｏｗｉｎｇｔｏｔｈｅｉｒａｎｔｉｆｕｎｇａｌａｎｄａｎｔｉｂａｃｔｅｒｉａｌａｃｔｉｖｉｔｉｅｓ1 ,2 ] .Ｔｈｅｙｃａｎａｌｓｏｂｅｕｓｅｄａｓａｎａｌｙｔｉｃａｌｒｅａｇｅｎｔｓ3 ]ａｎｄｅｘｔｒａｃｔｉｎｇａｇｅｎｔｓｆｏｒｍｅｔａｌｓａｌｔｓ4 ] .Ｍａｎｙｃｏｍｐｌｅｘｅｓｏｆｈｙｄｒａｚｉｄｅｓｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｚｅｄａｎｄｃｈａｒａｃｔｅｒｉｚｅｄ5]…
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| 关 键 词： | 稀土 配合物 荧光性能 电化学分析 合成 表征 |
Synthesis and Characterization of Rare Earth Complexes of Ferrocenylcarbonylhydrazine |
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| Bian Zhanxi,Dong Bin,Li Baoguo.Synthesis and Characterization of Rare Earth Complexes of Ferrocenylcarbonylhydrazine[J].Journal of Rare Earths,2002,20(5):434-437. |
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| Authors: | Bian Zhanxi Dong Bin Li Baoguo |
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| Abstract: | Rare earth complexes of ferrocenylcarbonylhydrazine Ln(FH)x(ClO4)3*nH2O (where Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, x=3; Ln = Er, Tm, Yb, Lu, x=4; n=2～6, FH=ferrocenylcarbonylhydrazin) were synthesized and characterized by elemental analyses, MS, IR and 1H NMR spectra. The ligand FH is bidentate, coordinating through the carbonyl oxygen and the amino nitrogen atom. The redox properties of the ligand and its complexes were investigated using cyclic voltammetric method. The solid state fluorescence spectra of Sm, Tb and Dy complexes were also studied. |
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| Keywords: | rare earths ferrocenylcarbonylhydrazine electrochemistry fluorescence |
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