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Selective oxidation of methane by dinitrogen monoxide on FeZSM-5 zeolites. Ab initio quantum chemical analysis |
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| Authors: | A V Arbuznikov G M Zhidomirov |
| Affiliation: | (1) Federal Scientific Center, Boreskov Institute of Catalysis, Prospekt Lavrentieva, 5, 630090 Novosibirsk, Russia |
| Abstract: | On the basis of ab initio quantum chemical calculations, we propose the structure and energetics of the species taking part in the selective oxidation of methane by dinitrogen monoxide on FeZSM-5 zeolites. The immediate oxidizing site is reasonably represented by a binuclear iron-hydroxide cluster with a peroxo-like fragment located between iron atoms. |
| Keywords: | FeZSM-5 zeolites selective oxidation of methane dinitrogen monoxide |
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