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Structural variations in layered alkaline earth metal cyclohexyl phosphonates
Authors:Ramaswamy Murugavel  Nayanmoni Gogoi
Affiliation:(1) Department of Chemistry, Indian Institute of Technology Bombay, Powai Mumbai, 400 076, India
Abstract:Two series of alkaline earth metal cyclohexyl phosphonates, M(C6H11PO3H)2(H2O) (M = Ca, Sr and Ba) (1–3) and M(C6H11PO3)(H2O) (M = Mg, Ca, Sr, and Ba) (4–7) have been synthesized under mild reaction conditions. All new compounds have been characterized using elemental analysis, IR, TGA and powder X-ray diffraction techniques. The molecular structure of compound 2 determined using single crystal X-ray diffraction technique reveals a layered polymeric structure.
Keywords:Metal phosphonates  layered compounds  X-ray structures
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