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Turning refuse plastic into multi-walled carbon nanotube forest
Authors:Eugene Oh  Jaegeun Lee  Seung-Ho Jung  Seungho Cho  Hye-Jin Kim  Sung-Hyun Lee  Kun-Hong Lee  Kyong-Hwa Song  Chi-Hoon Choi  Do Suck Han
Affiliation:1.Department of Chemical Engineering, Pohang University of Science and Technology(POSTECH), Pohang, 790-784, Korea;2.Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109, USA;3.National Center for Nanomaterials Technology (NCNT), Pohang, 790-784, Korea;4.Central Advanced Research and Engineering Institute, Hyundai Motor Company, Uiwang, 437-718, Korea
Abstract:A novel and effective method was devised for synthesizing a vertically aligned carbon nanotube (CNT) forest on a substrate using waste plastic obtained from commercially available water bottles. The advantages of the proposed method are the speed of processing and the use of waste as a raw material. A mechanism for the CNT growth was also proposed. The growth rate of the CNT forest was ∼2.5 μm min−1. Transmission electron microscopy images indicated that the outer diameters of the CNTs were 20–30 nm on average. The intensity ratio of the G and D Raman bands was 1.27 for the vertically aligned CNT forest. The Raman spectrum showed that the wall graphitization of the CNTs, synthesized via the proposed method was slightly higher than that of commercially available multi-walled carbon nanotubes (MWCNTs). We expect that the proposed method can be easily adapted to the disposal of other refuse materials and applied to MWCNT production industries.
Keywords:Carbon nanotubes  Microwave  Refuse plastics  Recycle
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