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润滑油抽出油的综合利用研究
引用本文:李文深,李晓鸥,刘洁,汪洋.润滑油抽出油的综合利用研究[J].化学与粘合,2009,31(1).
作者姓名:李文深  李晓鸥  刘洁  汪洋
作者单位:李文深,李晓鸥,刘洁,LI Wen-shen,LI Xiao-ou,LIU Jie(辽宁石油化工大学 石油化工学院,辽宁 抚顺,113001);汪洋,WANG Yang(辽阳石化分公司 烯烃厂,辽宁 辽阳,111003)  
摘    要:以减五线馏份油溶剂精制后的抽出油为原料,采用两种方法对它的综合利用进行了研究.一是以糠醛为溶剂研制符合一定标准的橡胶填充油;二是与发烟硫酸反应,研制石油磺酸钠.生产橡胶填充油的适宜操作条件为:抽提温度80℃.剂油比3.0,在此条件下产物收率为63.00%、芳烃含量为56.84%,符合某些企业橡胶填充油标准.生产石油磺酸较适宜的操作条件为:酸油比0.12,反应温度60℃,反应时间45min,在此条件下,石油磺酸收率为64.14%.与10%氢氧化钠中和反应,采用乙醇萃取出石油磺酸钠,测定其活性物含量为42.1%,可作为表面活性剂使用.所开发的方法无论是从经济效益还是从社会效益方面考虑,在我国都将有广泛的应用前景.

关 键 词:抽出油  综合利用  发烟硫酸  糠醛  橡胶填充油  石油磺酸钠

Study on Comprehensive Utilization of Extract Oil from Lubricating Oil
LI Wen-shen,LI Xiao-ou,LIU Jie , WANG Yang.Study on Comprehensive Utilization of Extract Oil from Lubricating Oil[J].Chemistry and Adhesion,2009,31(1).
Authors:LI Wen-shen  LI Xiao-ou  LIU Jie  WANG Yang
Affiliation:1.College of Petrochemical Technology;Liaoning University of Petroleum & Chemical Technology;Fushun 113001;China;2.Olefin Plant;Liaoyang Petrochemical Company;Liaoyang 111003;China
Abstract:Two methods were applied to research the comprehensive utilization of extract oil from solvent refining VGO No.5.One route was to produce the rubber filling oil which could meet certain standards with using furfural as the solvent.The other one was to obtain petroleum sodium sulfonate through sulfonation reaction with using oleum as sulfonating agent.The results of this experiment could be concluded as follows.The suitable conditions for producing rubber filling oil are determined,the extracting temperature...
Keywords:Extract oil  comprehensive utilization  oleum  furfural  rubber filling oil  petroleum sodium sulfonate  
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