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A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione) |
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| Authors: | Xian-Yin Wei Wei Chu Ru-Dan Huang Shao-Wen Zhang Hui Li Qin-Lei Zhu |
| Affiliation: | aThe Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, PR China |
| Abstract: | A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag–Ag interaction (2.9001 Å) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure. |
| Keywords: | 1,3-Thiazolidine-2-thione Single-crystal X-ray diffraction Strong Ag– Ag interaction Helical structure |
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