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天然高分子吸水材料的制备工艺与性能评价
引用本文:李丽,曹冲,单晓波.天然高分子吸水材料的制备工艺与性能评价[J].材料科学与工艺,2006,14(5):470-473,477.
作者姓名:李丽  曹冲  单晓波
作者单位:中国石油大学,化学化工学院,山东,东营,257061
摘    要:以天然薯粉为基本原料,采用直接聚合法和反相悬乳法两种不同方式,研究了淀粉接枝丙烯酸制备高叹水材料的工艺条件及产品性能,探讨了接枝剂用量、丙烯酸中和度、反应温度、反应时间等对产品吸水性能的影响,评价了下同方法制备所得吸水材料对淡、盐、肥水的吸水速率、吸水量、保水率和重复使用性能.研究结果表明,直接聚合法在简化工艺、降低成本等方面有明显优势,可制得吸水量约410g/g,吸盐水量约40g/g,吧乏吧水量约49g/g,且可多次重复使用的产品,具有广泛的工农业和市场应用前景.

关 键 词:吸水材料  淀粉  丙烯酸  接枝共聚反应
文章编号:1005-0299(2006)05-0470-04
收稿时间:2004-08-24
修稿时间:2004-08-24

Preparation and performance of natural high polymer absorbing water material
LI Li,CAO Chong,SHAN Xiao-bo.Preparation and performance of natural high polymer absorbing water material[J].Materials Science and Technology,2006,14(5):470-473,477.
Authors:LI Li  CAO Chong  SHAN Xiao-bo
Abstract:This study focuses on preparation and performance of water absorbing material made by starch graft acryl acid using natural starch and adopting two kinds of different ways. Effect of pharmaceutical consumption, acrylic acid neutralization degree, reaction temperature and time on water absorbing property were discussed and properties of materials prepared by different ways were evaluated, incldng absorption rate to fresh water, salt water, and manure water, water absorption, retention rate and repeatability. Results show that polymerization method is easier and low cost with the material having water absorption of 410 g/g, salt water absorption 40 g/g, manure water absorption 49 g/g and reusable property, which can be widely used in industrial and ag- ricultural field.
Keywords:absorb-water material  starch  acrylic acid  grafting copolymerization
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