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硬脂酸对纳米ZnO的有机表面修饰研究
引用本文:聂天琛,姚超,李锦春,杨绪杰,陆路德,汪信.硬脂酸对纳米ZnO的有机表面修饰研究[J].日用化学工业,2008,38(1):16-19.
作者姓名:聂天琛  姚超  李锦春  杨绪杰  陆路德  汪信
作者单位:1. 江苏工业学院,化工系,江苏,常州,213164
2. 江苏工业学院,化工系,江苏,常州,213164;南京理工大学,化工学院,江苏,南京,210094
3. 南京理工大学,化工学院,江苏,南京,210094
基金项目:江苏省科技攻关项目(No.BE2006373),江苏省博士后科研资助计划(0602020B),常州市科技攻关项目(No.CE2005016),常州青年科技人才培养计划资助项目(No.CQ2006009)
摘    要:利用硬脂酸对纳米ZnO进行有机表面修饰;采用红外光谱(IR)、热分析(TG-DTA)、透射电镜(TEM)、润湿性实验、分散性实验等手段对表面改性前后的纳米ZnO进行表征。红外光谱和TEM表明,在纳米ZnO表面包覆有硬脂酸的有机层;热分析显示,包覆量约为18.98%;润湿性实验及分散性实验表明,经硬脂酸改性的纳米ZnO的表面由亲水性变为亲油性。

关 键 词:纳米ZnO  硬脂酸  有机表面修饰
文章编号:1001-1803(2008)01-0016-04
收稿时间:2007-08-04
修稿时间:2007-09-21

Study of organic surface modification of nanosized ZnO With stearic acid
NIE Tian-chen,YA Chao,LI Jin-chun,YANG Xu-jie,LU Lu-de,WANG Xin.Study of organic surface modification of nanosized ZnO With stearic acid[J].China Surfactant Detergent & Cosmetics,2008,38(1):16-19.
Authors:NIE Tian-chen  YA Chao  LI Jin-chun  YANG Xu-jie  LU Lu-de  WANG Xin
Abstract:The surface organic modification of nanosized ZnO was studied.The prepared samples were characterized by FTIR,TG-DTA,HRTEM techniques as well as wettability test and dispersion test.According to the spectra of FTIR and TEM,results showed that stearic acid has been coated on the surface of nano-ZnO.Data from TG-DTA indicated that the mass fraction of stearic acid on the surface of nano-ZnO is about 18.98%.The wettability and dispersion tests showed that the surface property of nano-ZnO changed from hydrophilic to hydrophobic after the stearic acid modification.
Keywords:nanosized ZnO  stearic acid  organic surface modification
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