| 1-甲氧基-9,10-双(苯乙炔基)蒽的合成 |
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| 引用本文： | 李斌,苗蔚荣,程侣柏. 1-甲氧基-9,10-双(苯乙炔基)蒽的合成[J]. 精细化工, 1999, 16(2): 51-53 |
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| 作者姓名： | 李斌 苗蔚荣 程侣柏 |
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| 作者单位： | 大连理工大学精细化工(染料、表面活性剂)国家重点实验室,辽宁,大连,116012 |
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| 基金项目： | 国家自然科学基金!（29676005） |
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| 摘 要： | 由１－硝基蒽醌与甲酸钠作用生成１－甲氧基蒽醌，收率７５％。１．甲氧基蒽醌与苯乙炔基溴化镁在ＴＨＦ中回流２４ｈ，水解后的混合物不经分离直接与氯化亚锡的乙酸溶液反应３０ｍｉｎ，一步法合成了题示化合物，收率４６％。
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| 关 键 词： | 过氧草酸酯类化学发光 1-甲氧基-9,10,-双(苯乙炔基)蒽 |
Synthesis of 1-Mehtoxy-9,10-bis(phenylethynyl)anthracence |
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| LI Bin,Wei-rong,CHENG L-bai. Synthesis of 1-Mehtoxy-9,10-bis(phenylethynyl)anthracence[J]. Fine Chemicals, 1999, 16(2): 51-53 |
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| Authors: | LI Bin Wei-rong CHENG L-bai |
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| Abstract: | 1-Nitro-anthraquinone reacts with methanol and sodium to give 1 -methoxy- anthraquinone in 75 % yield, from which the bile compound is synthesized in a one-step route. Thus, 1 - methoxy - anthraquinone reacts with phenylethynyl magnesium bromide in THF under reflux for 24h, the mixture formed is hydrolyzed, then without separation, is treated with a solution of stannous chloride in acetic acid for 30min to give the tide compound with a yield of 46%. |
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| Keywords: | peroxyoxalate chemiluminescence 1 -methoxy-9 10-bis(phenylethynyl) anthracence |
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