| N,N''''-二正辛基-3,3''''-二硫代二丙酰胺的合成 |
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| 引用本文： | 王贤丰,杨建平,邬宁昆,刘晓梅. N,N''''-二正辛基-3,3''''-二硫代二丙酰胺的合成[J]. 农药, 2006, 45(10): 669-671 |
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| 作者姓名： | 王贤丰 杨建平 邬宁昆 刘晓梅 |
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| 作者单位： | 1. 宁波工程学院,浙江,宁波,315016
2. 宁波龙欣精细化工有限公司,浙江,宁波,313040 |
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| 基金项目： | 浙江省宁波市青年博士基金 |
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| 摘 要： | 研究了异噻唑啉酮的关键中间体N,N'-二正辛基-3,3'-二硫代二丙酰胺的合成。以丙烯酸甲酯为原料,经亲核加成、脱硫精制及酰胺化反应制得目的产物,总收率可达80%。同时详细讨论了反应物配比、反应温度及时间等因素对收率的影响。
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| 关 键 词： | 异噻唑酮 N,N'-二正辛基-3,3'-二硫代二丙酰胺 合成 |
| 文章编号： | 1006-0413(2006)10-0669-03 |
| 修稿时间： | 2006-04-20 |
Synthesis of N,N''''-di-n-octyl-3,3''''-dithiodipropionamide |
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| WANG Xian-feng,YANG Jian-ping,WU Ning-kun,LIU Xiao-mei. Synthesis of N,N''''-di-n-octyl-3,3''''-dithiodipropionamide[J]. Pesticides, 2006, 45(10): 669-671 |
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| Authors: | WANG Xian-feng YANG Jian-ping WU Ning-kun LIU Xiao-mei |
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| Abstract: | The key intermediate of N,N'-di-n-octyl-3,3'-dithiodipropionamide for preparing isothiazolone was synthe-sized starting from methyl acrylate by nucleophilic addition,purification with desulfurization and amidating,the totalyield reaches 80%.The effects on the yield by reaction agent relative ratio,reaction temperature,reaction time hadbeen also discussed. |
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| Keywords: | isothiazolone N N'-di-n-octyl-3 3'-dithiodipropionamide synthesis |
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