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PP/M-HOS/POE三元复合材料的界面改性与力学性能
引用本文:范宏,傅丽玲,卜志杨,李伯耿. PP/M-HOS/POE三元复合材料的界面改性与力学性能[J]. 塑料工业, 2004, 32(9): 36-38
作者姓名:范宏  傅丽玲  卜志杨  李伯耿
作者单位:浙江大学聚合反应工程国家重点实验室,浙江,杭州,310027
基金项目:国家杰出青年科学基金项目资助 (项目号 :2 0 12 5 617)
摘    要:采用马来酸酐接枝聚丙烯(PP-g-MAH)及马来酸酐接枝乙烯-1-辛烯共聚物(POE-g-MAH)为界面相容剂,利用熔融共混法制备PP/镁盐晶须(M—HOS)/POE三元复合材料,研究了PP-g-MAH及POE-g-MAH的用量及配比、M-HOS和POE的用量对三元复合材料力学性能的影响。结果表明:当PP/M-HOS/POE的质量比为100/10/20时,PP-g-MAH的最佳用量为3份;利用PP-g-MAH及POE-g-MAH作为复合相容剂可同时改善M-HOS与PP和POE的界面相容性,促进POE、M-HOS对PP的增韧补强作用,使三元复合材料的力学性能得到了明显的改善。

关 键 词:聚丙烯 马来酸酐接枝聚丙烯 马来酸酐接枝乙烯-1-辛烯共聚物 镁盐晶须
文章编号:1005-5770(2004)09-0036-03
修稿时间:2004-05-28

Modification of Interface and Mechanical Properties of PP/Magnesium Hydrate Whisker/POE Composite
FAN Hong,FU Li-ling,BU Zhi-Yang,Li Bo-Geng. Modification of Interface and Mechanical Properties of PP/Magnesium Hydrate Whisker/POE Composite[J]. China Plastics Industry, 2004, 32(9): 36-38
Authors:FAN Hong  FU Li-ling  BU Zhi-Yang  Li Bo-Geng
Abstract:Taking PP-g-MAH and POE-g-MAH as interfacial compatibilizers, PP/magnesium hydrate whisker (M-HOS)/ POE composite was prepared by means of melt blending. The effects of the content and compounding ratio of PP-g-MAH and POE-g-MAH, and the content of M-HOS and POE on the mechanical properties of the composite were studied. The results showed when the mass ratio of PP/M-HOS/POE was 100/10/20, the optimum content of the compatibilizer PP-g-MAH was 3 phr; the interfacial compatibility of M-HOS with PP and POE could be improved by using PP-g-MAH and POE-g-MAH as compounded compatibilizeres, resulted in an improvement of the toughening and strengthening of the composite, making the mechanical properties of the composite improved obviously.
Keywords:PP  PP-g-MAH  POE-g-MAH  Magnesium Hydrate Whisker
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