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N2 decomposition by hot wire and N2 post-deposition treatment on hydrogenated microcrystalline silicon thin films
Authors:Koji Mazaki  Akihiko Kitagawa
Affiliation:a Department of Electrical Engineering and Computer Science, Nagoya University, C3-1(631) Chikusa, Nagoya 464-8603, Japan
b Department of Electric and Electronic Engineering, Gifu University, Yanagido, Gifu, 501-1193, Japan
Abstract:Post-deposition treatment of hydrogenated microcrystalline silicon (µc-Si:H) was carried out using a hot wire in atmospheres of N2, N2/H2 or H2 and the states of the bonds in the µc-Si:H films were investigated using X-ray photoelectron spectroscopy. For the µc-Si:H film treated in N2 at the filament temperature (Tf) of 1600 °C, a weak N1s peak was observed. It increased slightly with increasing Tf from 1600 to 1900 °C and increased dramatically with increasing Tf from 1900 to 2000 °C. The N1s peak of the µc-Si:H film treated in N2/H2 at Tf = 2000  °C was one order of magnitude lower than that in N2 at Tf = 2000 °C. These findings indicate that N2 molecules decompose on the heated filament and that the addition of H2 prevents N2 decomposition.
Keywords:Microcrystalline silicon  N2 decomposition  Thin films  Hot-wire  Post-deposition treatment  X-ray photoelectron spectroscopy  Fourier-transform infrared(FT-IR)
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