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Improving light efficiency of white polymer light emitting diodes by introducing the TPBi exciton protection layer
Authors:Sang Baie Shin  Hak Min Lee  Myoung Seon Gong  Jun Yeop Lee  Ho Jung Chang
Affiliation:a Department of Electronics Engineering, Dankook University, Cheonan, Chungnam, 330-714, South Korea
b Department of Chemistry, Dankook University, Cheonan, Chungnam, 330-714, South Korea
c Department of Polymer Science, Dankook University, Suwon, Gyonggi, 443-760, South Korea
d School of Mechatronics Engineering, Korea University of Technology and Education, Cheonan, Chungnam, 330-708, South Korea
Abstract:We fabricated and evaluated the efficient white polymer light emitting diode (WPLED) by introducing TPBi exciton protection layer with ITO/PEDOT:PSS/PFO:MEH-PPV/TPBi/LiF/Al structure. PFO and MEH-PPV were prepared by the spin coating as the light emitting host and guest materials. TPBi was used as exciton protection material. The dependences of the MEH-PPV concentrations into the PFO (PFO:MEH-PPV) on the optical and electrical properties of the WPLEDs were investigated. The effect of the introduction of TPBi layer was studied by means of the property comparison between the samples with and without TPBi layer. The maximum luminance with 1480 cd/m2 was obtained at the MEH-PPV concentration of 1.0 wt.% for the ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al structure. In addition, the maximum luminance and current efficiency of the WPLED with TPBi layer were 7560 cd/m2 at 12 V and 7.8 cd/A at 10 cd/m2, respectively. The CIE color coordinates for WPLED with 1.0 wt.% MEH-PPV concentration was found to be (x, y) = (0.36, 0.33), showing pure white color.
Keywords:White polymer light emitting diode   Spin coating   Luminance   PFO   MEH-PPV   TPBi   Exciton protection layer
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