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| 两种卷烟粘合剂热裂解产物研究 | |
| 引用本文： | 杨卫花,张承明,武怡,曾晓鹰,袁汝红,张承聪.两种卷烟粘合剂热裂解产物研究[J].云南化工,2008,35(4). |
| 作者姓名： | 杨卫花 张承明 武怡 曾晓鹰 袁汝红 张承聪 |
| 作者单位： | 1. 云南烟草科学研究院烟草化学研究室,云南,昆明,650106;云南大学,化学科学与工程学院,云南,昆明,650091 2. 云南烟草科学研究院烟草化学研究室,云南,昆明,650106 3. 红云集团技术中心,云南,昆明,650202 4. 云南大学,化学科学与工程学院,云南,昆明,650091 |
| 摘 要： | 模拟卷烟燃烧条件,选择200℃到800℃之间的4个不同温度,在空气存在的条件下对VAE(聚醋酸乙烯)型和淀粉型的的两种卷烟粘合剂进行热裂解,热裂解产物用气相色谱-质谱联用方法检测。得出粘合剂在不同的温度下裂解产物不同;不同种类的粘合剂裂解产物不同;温度升高,能被检测的物质种类增多。在不同条件下,VAE型粘合剂的裂解产物主要以苯衍生物及多环烃(PAHs)为主;淀粉型的粘合剂裂解产物则主要以呋喃类化合物为主。 |
| 关 键 词： | 热裂解 气相色谱-质谱联用 卷烟粘合剂 |
Study on the Pyrolytic Products from Two Cigarette Adhesives |
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| YANG We-hua,ZHANG Cheng-ming,WU Yi,ZENG Xiao-ying,YUAN Ru-hong,ZHANG Cheng-cong.Study on the Pyrolytic Products from Two Cigarette Adhesives[J].Yunnan Chemical Technology,2008,35(4). | |
| Authors: | YANG We-hua ZHANG Cheng-ming WU Yi ZENG Xiao-ying YUAN Ru-hong ZHANG Cheng-cong |
| Abstract: | Pyrolytic products of two types of cigarette adhesives in the presence of air were studied,which simulated the burning condition of cigarette at 4 different temperatures,from 200 to 800℃.Gas chromatography-mass spectrometry was used to analyze the pyrolytic products,and result showed that the pyrolytic products of 2 different cigarette adhesives were different at different temperatures.The kinds of compounds could be detected were increasing with the increase of temperature.The major pyrolysates from polyvinyl acetate-based adhesive were aromatic hydrocarbons and polynuclear hydrocarbons,whereas furans were detected from starch-based adhesive. |
| Keywords: | pyrolysis Gas Chromatography-Mass Spectrometry cigarette adhesive |
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