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低熔点硫酸盐对软质PVC的阻燃与消烟性能研究
引用本文:田春明,王海,等.低熔点硫酸盐对软质PVC的阻燃与消烟性能研究[J].中国塑料,2003,17(2):84-89.
作者姓名:田春明  王海
作者单位:河北大学化学与环境科学学院 河北保定071002 (田春明,王海,郭花枝),河北大学化学与环境科学学院 河北保定071002(徐建中)
摘    要:制得的硫酸盐混合物熔点低,在适当温度下熔融时,能有效地保护PVC降解过程中形成的剩磷,从而能提高剩碳率,提高阻燃与消烟性能。氧指数、烟密度、DTA、TG、SEM等证明了低熔点的硫酸盐是一种优良的填料性的、具有阻燃与消烟性的阻燃消烟剂,具有很好的消烟性,当添加量达40份时,烟密度能下降45%。研究表明其对力学性能的影响比其它填料小。

关 键 词:低熔点硫酸盐  软质PVC  阻燃  消烟性能  研究  聚氯乙烯

Study on the Flame Retardant and Smoke Suppressant Property of Flexible PVC
TIAN Chun-ming,WANG Hai,GUO Hua-zhi,XU Jian-zhong.Study on the Flame Retardant and Smoke Suppressant Property of Flexible PVC[J].China Plastics,2003,17(2):84-89.
Authors:TIAN Chun-ming  WANG Hai  GUO Hua-zhi  XU Jian-zhong
Abstract:Mixture made from sulfate has low melting point.While melting at right temperature,it can protect the residual carbon produced in the degradation of PVC,thus increasing the residual carbon amount and the flame retardancy and smoke suppression.Tests of Limiting Oxygen Index,Smoke Density Rating(SDR) and DTA-TG and SEM prove that the sulfate with low melting point is a kind of flame retardant and smoke suppressant with excellent flame retardancy and smoke suppression.The SDR of PVC compound with 40 phr sulfate decreased by 45 %.The study also verified that the sulfate had less effect on the mechanical properties of PVC compound than other fillers.
Keywords:poly(vinyl chloride)  low melting sulfate  flame retardant  smoke suppressant
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