| 高效液相色谱法和质谱法分析重烷基苯磺酸钠的族组成 |
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| 引用本文： | 王惠敬,王佩维,关景才. 高效液相色谱法和质谱法分析重烷基苯磺酸钠的族组成[J]. 日用化学工业, 2008, 38(5) |
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| 作者姓名： | 王惠敬 王佩维 关景才 |
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| 作者单位： | 中国日用化学工业研究院,山西,太原,030001;中国日用化学工业研究院,山西,太原,030001;中国日用化学工业研究院,山西,太原,030001 |
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| 摘 要： | 采用电喷雾质谱法得到了重烷基苯磺酸钠的相对分子质量分布,经过对质谱图解析确定了各组峰的族组成归属和烷基碳数分布;用高效液相色谱使重烷基苯磺酸钠各族组成得到分离,并结合质谱分析结果和族组成的极性规律判断出各组峰的族组成归属.用面积归一化法得出A段和B段重烷基苯磺酸钠的各族组成的质量分数,相对标准偏差0.58%～4.72%,各族组成质量浓度与峰面积呈良好的线性关系,证明了用面积归一化法的可行性.
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| 关 键 词： | 重烷基苯磺酸钠 高效液相色谱法 电喷雾质谱法 族组成 |
Determination of group composition of sodium heavy alkylbenzene sulfonate by HPLC and electron spray ionization- mass spectrometry |
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| WANG Hui-jing,WANG Pei-wei,GUAN Jing-cai. Determination of group composition of sodium heavy alkylbenzene sulfonate by HPLC and electron spray ionization- mass spectrometry[J]. China Surfactant Detergent & Cosmetics, 2008, 38(5) |
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| Authors: | WANG Hui-jing WANG Pei-wei GUAN Jing-cai |
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| Abstract: | Molecular distribution of sodium heavy alkylbenzene sulfonate was obtained by electron spray ionization-mass spectrometry(ESI-MS).Through the analysis of mass spectra,the group composition and carbon number distribution of each peak group were identified.Using HPLC,constituents of each group were separated.By combining the ESI-MS analysis results and the polarity rule of all group composition,the normalization of each group was confirmed.Mass fraction of each group composition of sodium heavy alkylbenzene sulfonate(fraction A and fraction B) were obtained by area normalization method.The standard deviation was found as 0.58%~4.72%.The mass fraction of each constituent shows good linearity with the corresponding peak area.It shows that the use of area normalization method in this case is feasible. |
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| Keywords: | sodium heavy alkylbenzene sulfonate high performance liquid chromatography electron spray ionization-mass spectrometry homologue group |
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