| 对-羟基苯海因生产过程中含酚废水的处理 |
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| 引用本文： | 郭秀斌,胡国田,徐世斌,王清海.对-羟基苯海因生产过程中含酚废水的处理[J].精细化工,2002,19(5):266-267,272. |
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| 作者姓名： | 郭秀斌 胡国田 徐世斌 王清海 |
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| 作者单位： | 1. 河北师范大学化学学院,河北石家庄,050091
2. 石家庄三合化工有限公司,河北石家庄051430 |
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| 摘 要： | 用蒸馏—萃取—大孔树脂吸附的工艺处理化学—酶法生产D 对 羟基苯甘氨酸过程产生的含酚废水 ,苯酚回收率接近 10 0 % ,每 2t废水可回收苯酚 16 0kg ,稀盐酸 170 0kg。蒸馏后的母液套用于对 羟基苯海因 (HPH)的合成 ,可使其收率提高 10 % ,回收得到的酚钠可用于合成
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| 关 键 词： | 蒸馏 萃取 吸附 苯酚 |
| 文章编号： | 1003-5214(2002)05-0266-03 |
Treatment of Phenol-bearing Wastewater from p-Hydroxyphenylhydantoin Production |
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| GUO Xiu bin ,HU Guo tian ,XU Shi bin ,WANG Qing hai.Treatment of Phenol-bearing Wastewater from p-Hydroxyphenylhydantoin Production[J].Fine Chemicals,2002,19(5):266-267,272. |
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| Authors: | GUO Xiu bin HU Guo tian XU Shi bin WANG Qing hai |
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| Affiliation: | GUO Xiu bin 1,HU Guo tian 2,XU Shi bin 2,WANG Qing hai 2 |
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| Abstract: | Distillation,extraction and absorption with macroporous resin were used to treat phenol bearing wastewater from D p hydroxyphenylglycine production by chemical enzymatic method.The rate of phenol removal could achieve nearly 100%.160 kg phenol and 1700 kg dilute hydrochloric acid were obtained by treating the wastewater from 1000 kg p hydroxyphenylhydantoin production.The mother liquor of distillation could be used in the synthesis of p hydroxyphenylhydantoin to increase by 10% the yield.The recovered sodium phenolate could be reused in the synthesis. |
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| Keywords: | distillation extraction absorption phenol |
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