| 小药量含能材料热安全性判据总标准偏差的分析（英） |
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| 引用本文： | 胡荣祖,赵凤起,高红旭,仪建华,徐司雨.小药量含能材料热安全性判据总标准偏差的分析（英）[J].含能材料,2011,19(2):132-137. |
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| 作者姓名： | 胡荣祖 赵凤起 高红旭 仪建华 徐司雨 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 基金项目： | Science and Technology Foundation of National Defence Key Laboratory of Propellant and Explosive Combustion of China(9140C3501010601) |
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| 摘 要： | 借助M(NTO)n·mH2O(M=Ba,n=1,m=3;M=Li,n=1,m=2;M=Ca,n=2,m=4;M=Na,n=m=1;M=Co,Mg,n=2,m=8;M=Ce,Pr,Gd,n=3,m=7;M=Tb,Dy,n=3,m=5;M=Y,Yb,n=3,m=6;NTO=3-nitro-1,2,4-triazol-5-one)的摩尔用量(a)、水溶液浓度(b)及由Calvet微热量计所得的溶解过程热效应(Q)和摩尔溶解焓(ΔdissH),得到了描述这些NTO金属配合物的微分溶解焓(ΔdifHmθ)、标准摩尔溶解焓ΔdissHmθ(b=0)]、相对表观摩尔焓(ΔdissHapparent)、相对偏摩尔焓(ΔdissHpartial)和稀释焓(ΔdilH1,2)的5个经验式。
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| 关 键 词： | 物理化学 焓 溶解性质 NTO 金属配合物 |
| 收稿时间： | 5/19/2010 3:33:18 PM |
| 修稿时间： | 2010/12/22 0:00:00 |
Deviation of Thermal Safety Criteria for Small-scale Energetic Materials |
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| HU Rong-zu,ZHAO Feng-qi,GAO Hong-xu,YI Jian-hua and XU Si-yu.Deviation of Thermal Safety Criteria for Small-scale Energetic Materials[J].Chinese Journal of Energetic Materials,2011,19(2):132-137. |
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| Authors: | HU Rong-zu ZHAO Feng-qi GAO Hong-xu YI Jian-hua and XU Si-yu |
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| Affiliation: | (Xi′an Modern Chemistry Research Institute,Xi′an 710065,China) |
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| Abstract: | With the help of the amount of the complex (a ), the concentration of the solution (b ), the heat effect of dissolution process ( Q) and the molar enthalpy of dissolution in water of M(NTO)n.mH2O(M=Ba, n=1, m=3; M=Li, n=1, m=2; M=Ca, n=2, m=4; M=Na, n=m=1; M=Co, Mg, n=2, m=8; M=Ce, Pr, Gd, n=3, m=7; M=Tb, Dy, n=3, m=5; M=Y, Yb, n=3, m=6; NTO=3-nitro-1, 2, 4-triazol-5-one) obtained by a Calvet microcalorimeter, five empirical formulae describing the differential enthalpy of dissolution, standard molar enthalpy of dissolution , relative apparent molar enthalpy, relative partial molar enthalpy and enthalpies of dilution in water of these metal complexes of NTO were obtained. |
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| Keywords: | physical chemistry thermal safety criteria overall standard deviation energetic materials |
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