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复合正极材料Li2MnO3-LiMO2的研究现状
引用本文:陈杨英,耿世达.复合正极材料Li2MnO3-LiMO2的研究现状[J].电池,2012,42(2):110-113.
作者姓名:陈杨英  耿世达
作者单位:大连丽昌新材料有限公司锂离子动力及储能电池实验室,辽宁 大连,116422
摘    要:综述了锂离子电池复合正极材料Li2MnO3-LiMO2(M=Co、Ni和Mn)的研究进展;重点介绍了首次充放电过程中组成及结构的变化以及为改善首次充放电效率和倍率性能所进行的后处理.通过电化学活化、酸处理、表面包覆等方法处理后,该类材料的首次充放电不可逆容量可降低,倍率性能及循环稳定性可得到很大提高.

关 键 词:锂离子电池  正极材料  Li2MnO3-LiMO2  充放电机理  后处理

Research status quo of Li2MnO3-LiMO2 composite cathode materials
CHEN Yang-ying , GENG Shi-da.Research status quo of Li2MnO3-LiMO2 composite cathode materials[J].Battery Bimonthly,2012,42(2):110-113.
Authors:CHEN Yang-ying  GENG Shi-da
Affiliation:(Laboratory of Lithium Ion Battery for Power and Energy Storage,Greentech AdvancedMaterials Co.,Ltd.,Dalian,Liaoning 116422,China)
Abstract:Research progress in composite materials Li2MnO3-LiMO2(M=Co,Ni,Mn)as promising cathode candidates for Li-ion battery was summarized.Particularly,the changes of composition and structure during initial charge/discharge process and post-treatment methods of these materials and their effects for improvement of coulombic efficiency of initial charge/discharge and rate capability were highlighted.After post-treatment with electrochemical activation,dilute acid,surface coating etc,the irreversible capacity of the first charge/discharge cycle was reduced,rate performance and cycle stability were improved.
Keywords:Li-ion battery  cathode material  Li2MnO3-LiMO2  charge/discharge mechanism  post-treatment
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