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胜利油田纯梁原油乳状液稳定性研究
引用本文:曹加花,徐志成,宫清涛,靳志强,张磊,张路,. 胜利油田纯梁原油乳状液稳定性研究[J]. 石油学报(石油加工), 2016, 32(5): 997-1004. DOI: 10.3969/j.issn.1001-8719.2016.05.018
作者姓名:曹加花  徐志成  宫清涛  靳志强  张磊  张路  
作者单位:1中国科学院 理化技术研究所, 北京 100190; 2中国科学院大学, 北京 100049;3武汉理工大学 化学化工与生命科学学院, 湖北 武汉 430070
基金项目:国家科技重大专项(2016ZX05011-003)和国家自然科学资金项目(51373192)资助
摘    要:利用LUMisizer LS610稳定性分析仪研究了胜利油田纯梁原油乳状液的稳定性和液滴直径的变化规律,考察了不同结构破乳剂对乳状液稳定性的影响。结果表明,在离心力的作用下,大液滴沉降得更快,导致靠近样品池底部位置的透光率偏高,大液滴较多。直链的非离子破乳剂BP01吸附能力较强,在低质量分数时即表现出高效的破乳能力;支链非离子破乳剂PA05由于其特殊的支链结构,吸附能力较弱,对乳状液的破坏能力略弱于BP01;阳离子破乳剂HY01在离心力场中对乳状液稳定性的影响不明显。

关 键 词:乳状液  稳定性  稳定性分析仪  破乳剂  积分透光率  液滴直径  
收稿时间:2015-07-29

Study on the Emulsion Stability of Shengli Oilfield Chunliang Crude Oil
CAO Jiahua,XU Zhicheng,GONG Qingtao,JIN Zhiqiang,ZHANG Lei,ZHANG Lu. Study on the Emulsion Stability of Shengli Oilfield Chunliang Crude Oil[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2016, 32(5): 997-1004. DOI: 10.3969/j.issn.1001-8719.2016.05.018
Authors:CAO Jiahua  XU Zhicheng  GONG Qingtao  JIN Zhiqiang  ZHANG Lei  ZHANG Lu
Affiliation:1Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;2University of Chinese Academy of Sciences, Beijing 100049, China; 3School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China
Abstract:The emulsion stability of Shengli oilfield Chunliang crude oil and variation of droplet diameter were investigated by using LUMisizer in different conditions. At the same time, the influence of demulsifiers with different structures on the stability of emulsion was also explored. The results showed that the droplets with large diameter settled faster, which resulted in the higher transmission and larger droplet at the bottom of sample cell. The linear demulsifier BP01 had effective ability to destroy the crude emulsion at low mass fractions because of its strong adsorption at oil water interface. On the stability of crude emulsion the demulsifiers PA05 with branched structure had weaker effect than BP01, while cationic reversed phase demulsifiers HY01 had little effect in centrifugal force field.
Keywords:emulsion  stability  LUMisizer  demulsifiers  integral transmission  drop diameter  
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