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甲醇制丙烯工艺路线技术经济分析
引用本文:张灵玲,雍晓静,廖祖维,王林,蒋斌波,王靖岱,阳永荣,焦洪桥.甲醇制丙烯工艺路线技术经济分析[J].石油学报(石油加工),2016,32(6):1186-1194.
作者姓名:张灵玲  雍晓静  廖祖维  王林  蒋斌波  王靖岱  阳永荣  焦洪桥
作者单位:1. 浙江大学 化学工程与生物工程学院 化学工程联合国家重点实验室,浙江 杭州 310027; 2. 神华宁夏煤业集团,宁夏 银川 750411
基金项目:国家自然科学基金项目(61590925)、“863”国际合作项目(2015DFA40660)和浙江省自然科学基金项目(LY14B060007)资助
摘    要:以49万t规模甲醇制丙烯(MTP)流程为研究对象,考察了高温醚化+前脱丁烷、高温醚化+前脱丙烷、低温醚化+前脱丁烷、低温醚化+前脱丙烷4种技术组合的经济性能。在4种技术组合中,低温醚化+前脱丙烷的技术组合能耗(502 MW)、公用工程费用(加热冷却公用工程费用622×108 RMB yuan/a),CO2排放量(2023×109 kg/a),〖JP〗能效(07107)等指标更优,更具有竞争力。产品分离过程的能耗占全流程能耗的50%以上,因此分离单元的优化改进是提高甲醇制丙烯流程能效的关键。

关 键 词:前脱丙烷分离流程  前脱丁烷分离流程  高温醚化  低温醚化  节能  减排  
收稿时间:2015-11-30

Techno-Economic Analysis of Methanol to Propylene Process
ZHANG Lingling,YONG Xiaojing,LIAO Zuwei,WANG Lin,JIANG Binbo,WANG Jingdai,YANG Yongrong,JIAO Hongqiao.Techno-Economic Analysis of Methanol to Propylene Process[J].Acta Petrolei Sinica (Petroleum Processing Section),2016,32(6):1186-1194.
Authors:ZHANG Lingling  YONG Xiaojing  LIAO Zuwei  WANG Lin  JIANG Binbo  WANG Jingdai  YANG Yongrong  JIAO Hongqiao
Affiliation:1. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China; 2. Shenhua Ningxia Coal Group, Yinchuan 75041, China
Abstract:Based on the 049 million tons scale methanol to propylene (MTP) process, the technology combinations of high temperature methanol to dimethyl ether (MTD) and front end debutanization separation process, high temperature MTD and front end depropanization separation process, low temperature MTD and front end debutanization separation process, low temperature MTD and front end depropanization separation process were studied. In the four combinations, the combination of low temperature MTD and front end depropanization separation has the lowest energy consumption (502 MW), the lowest energy cost (622×108 RMB yuan/a), the lowest CO2 emissions(2023×109 kg/a) and the highest energy efficiency (07107), thus, it is most competitive. The energy consumption ratio of product separation unit exceeded 50%, so that the energy conservation and improvement of this part will be the key point for enhancement of MTP process.
Keywords:front-end depropanization separation  front-end debutanization separation  high temperature methanol to dimethyl ether  low temperature methanol to dimethyl ether  energy conservation  emission reduction  
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