Affiliation: | 1. Department of Physics, Bielefeld University, 33615 Bielefeld, Germany
Leibniz IFW Dresden, Institute for Metallic Materials, 01069 Dresden, Germany;2. Department of Physics, University of Duisburg-Essen, 47057 Duisburg, Germany;3. Department of Chemistry, University of Duisburg-Essen, 45141 Essen, Germany;4. Department of Physics, Bielefeld University, 33615 Bielefeld, Germany;5. Leibniz IFW Dresden, Institute for Metallic Materials, 01069 Dresden, Germany;6. Department of Chemistry, University of Duisburg-Essen, 45141 Essen, Germany
Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Carl-Benz-Straße 199, 47057 Duisburg, Germany |
Abstract: | Three-dimensional topological insulators (3D TI) exhibit conventional parabolic bulk bands and protected Dirac surface states. A thorough investigation of the different transport channels provided by the bulk and surface carriers using macroscopic samples may provide a path toward accessing superior surface transport properties. Bi2Te3 materials make promising 3D TI models; however, due to their complicated defect chemistry, these materials have a high number of charge carriers in the bulk that dominate the transport, even as nanograined structures. To partially control the bulk charge carrier density, herein the synthesis of Te-enriched Bi2Te3 nanoparticles is reported. The resulting nanoparticles are compacted into nanograined pellets of varying porosity to tailor the surface-to-volume ratio, thereby emphasizing the surface transport channels. The nanograined pellets are characterized by a combination of resistivity, Hall- and magneto-conductance measurements together with (THz) time-domain reflectivity measurements. Using the Hikami-Larkin-Nagaoka (HLN) model, a characteristic coherence length of ≈200 nm is reported that is considerably larger than the diameter of the nanograins. The different contributions from the bulk and surface carriers are disentangled by THz spectroscopy, thus emphasizing the dominant role of the surface carriers. The results strongly suggest that the surface transport carriers have overcome the hindrance imposed by nanoparticle boundaries. |