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Tuning the Chiral Structures from Self-Assembled Carbohydrate Derivatives (Small 25/2023)
Authors:Yawen Yao  Xintong Meng  Cheng Li  Katrien V. Bernaerts  Kai Zhang
Affiliation:1. Sustainable Materials and Chemistry, Department of Wood Technology and Wood-Based Composites, University of Göttingen, Büsgenweg 4, 37077 Göttingen, Germany

Sustainable Polymer Synthesis, Aachen-Maastricht Institute for Biobased Materials (AMIBM), Maastricht University, Urmonderbaan 22, Geleen, 6167 RD Netherlands;2. Sustainable Materials and Chemistry, Department of Wood Technology and Wood-Based Composites, University of Göttingen, Büsgenweg 4, 37077 Göttingen, Germany;3. Sustainable Polymer Synthesis, Aachen-Maastricht Institute for Biobased Materials (AMIBM), Maastricht University, Urmonderbaan 22, Geleen, 6167 RD Netherlands

Abstract:Carbohydrates have been regarded as one of the most ideally suited candidates for chirality study via self-assembly owning to their unique chemical structures, abundance, and sustainability. Much efforts have been devoted to design and synthesize diverse carbohydrate derivatives and self-assemble them into various supermolecular morphologies. Nevertheless, still inadequate attention is paid to deeply and comprehensively understand how the carbohydrate structures and self-assembly approaches affect the final morphologies and properties for future demands. Herein, to fulfill the need, a range of recently published studies relating to the chirality of carbohydrates is reviewed and discussed. Furthermore, to tune the chirality of carbohydrate-based structures on both molecular and superstructural levels via chirality transfer and chirality expression, the designing of the molecules and choosing of the proper approaches for self-assembly are elucidated.
Keywords:carbohydrate  chirality  derivative  molecular design  self-assembly
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